Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements     

Jin Li  Suo‐han Tang  Xiang‐kun Zhu  Zhi‐hong Li  Shi‐Zhen Li  Bin Yan  Yue Wang  Jian Sun  Yao Shi  Aiguo Dong  Nick S. Belshaw  Xingchao Zhang  Sheng‐ao Liu  Ji‐hua Liu  Deli Wang  Shao‐yong Jiang  KeJun Hou  Anthony S. Cohen 《Geostandards and Geoanalytical Research》2019,43(1):163-175

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).  相似文献   

Zircon U-Pb-Hf constraints from Gongga Shan granites on young crustal melting in eastern Tibet     

Nick M.W.Roberts  Michael P.Searle 《地学前缘(英文版)》2019,10(3):885-894

The Gongga Shan batholith is a complex granitoid batholith on the eastern margin of the Tibetan Plateau with a long history of magmatism spanning from the Triassic to the Pliocene. Late Miocene-Pliocene units are the youngest exposed crustal melts within the entire Asian plate of the Tibetan Plateau.Here, we present in-situ zircon Hf isotope constraints on their magmatic source, to aid the understanding of how these young melts were formed and how they were exhumed to the surface. Hf isotope signatures of Eocene to Pliocene zircon rims(ε_Hf(t)=-4 to +4), interpreted to have grown during localised crustal melting, are indicative of melting of a Neoproterozoic source region, equivalent to the nearby exposed Kangding Complex. Therefore, we suggest that Neoproterozoic crust underlies this region of the Songpan-Ganze terrane, and sourced the intrusive granites that form the Gongga Shan batholith. Localised young melting of Neoproterozoic lower or middle crust requires localised melt-fertile lithologies. We suggest that such melts may be equivalent to seismic and magnetotelluric low-velocity and high-conductivity zones or "bright spots" imaged across much of the Tibetan Plateau. The lack of widespread exposed melts this age is due either to the lack of melt-fertile rocks in the middle crust, the very low erosion level of the Tibetan plateau, or to a lack of mechanism for exhuming such melts. For Gongga Shan, where some melting is younger than nearby thermochronological ages of low temperature cooling, the exact process and timing of exhumation remains enigmatic, but their location away from the Xianshuihe fault precludes the fault acting as a conduit for the young melts. We suggest that underthrusting of dry granulites of the lower Indian crust(Archaean shield) this far northeast is a plausible mechanism to explain the uplift and exhumation of the eastern Tibetan Plateau.  相似文献   

Preserved organic matter in a fossil Ocean Continent Transition in the Alps: the example of Totalp,SE Switzerland     

Tsvetomila Mateeva  George A. Wolff  Gianreto Manatschal  Suzanne Picazo  Nick J. Kusznir  John Wheeler 《Swiss Journal of Geoscience》2017,110(2):457-478

Evidence from ultraslow spreading mid-ocean ridges and both fossil and present-day Ocean–Continent Transitions (OCT) demonstrates that mantle serpentinization resulting from the interaction of mantle rock and water during tectonic exhumation is widespread. Observations at white smokers in modern ocean settings suggest that methane produced by serpentinization can support methanotrophic bio-systems, which use methane as the only source of carbon. An important question is whether such bio-systems are more generally pervasive in their association with serpentinized mantle in the subsurface. In this study, we examined whether there is evidence for such a methanotrophic system in exhumed serpentinized mantle at a magma-poor rifted continental margin, by probing for characteristic biological markers in these and associated sedimentary rocks in the Totalp unit of SE Switzerland. This unit represents a remnant of the former OCT of the southern Alpine Tethyan margin and was chosen because of its mild Alpine tectonic and low-grade metamorphic overprint during Alpine orogeny, hence giving potential for the preservation of indigenous organic matter (OM). Totalp samples are characterized by low organic carbon contents of 11–647 ppm. The majority of the samples contain hydrocarbons in the form of n-alkanes in the range C₁₇–C₃₆. Some sediments contain isoprenoids, for example pristane and phytane and a suite of steranes that are consistent with a marine origin for the OM preserved in the rocks. Traces of marine planktonic and bacterial OM are preserved in the serpentinized mantle and overlying sediments of this ancient Tethyan OCT, but there is no evidence that the OM has been generated from methanotrophic bio-systems.  相似文献   

Application of the Ordered Weighted Averaging (OWA) method to the Caspian Sea conflict   总被引：1，自引：0，他引：1  

Hojjat Mianabadi  Majid Sheikhmohammady  Erik Mostert  Nick Van de Giesen 《Stochastic Environmental Research and Risk Assessment (SERRA)》2014,28(6):1359-1372

This study proposes a promising allocation mechanism of the Caspian Sea natural resources, which are presently shared among five countries. To date, these nations have been unable to reach an allocation agreement. We apply a methodology to propose the most appropriate solution under different risk attitudes of the states. This research is different from other studies regarding the Caspian Sea negotiations in that it employs risk-based fuzzy multi attribute decision making methods for simulating the risk attitudes or optimism/pessimism degrees of the decision makers. The ordered weighted averaging (OWA) approach, which considers the optimism/pessimism degree quantitatively, is used to take into account the effects of different risk attitudes of the negotiators on the final outcome. We demonstrate how one could obtain a range of alternatives under different multi attribute and risk attitudes. The induced OWA (IOWA) method is also used to determine the relative power of these states bordering the Caspian Sea by considering several attributes, including different risk attitudes of agents. Results indicate that taking into account the risk attitude (prone, neutral, averse) of the states can affect the overall ranking of the proposed solutions. The findings from this study may facilitate negotiation regarding the most preferred allocation mechanism for the Caspian Sea.  相似文献   

Alternative water management options to reduce vulnerability for climate change in the Netherlands   总被引：1，自引：0，他引：1  

Rutger de Graaf  Nick van de Giesen  Frans van de Ven 《Natural Hazards》2009,51(3):407-422

Urbanization, land subsidence and sea level rise will increase vulnerability of the urbanized low-lying areas in the western part of the Netherlands. In this article possibilities are explored to reduce vulnerability of these areas by implementing alternative water management options. Two main water management fields are distinguished, water supply and flood control. A four-component vulnerability framework is presented that includes threshold capacity, coping capacity, recovery capacity, and adaptive capacity. By using the vulnerability framework it is shown that current water supply and flood control strategies in the Netherlands focus on increasing threshold capacity by constructing higher and stronger dikes, improved water storage and delivery infrastructure. A complete vulnerability decreasing strategy requires measures that include all four capacities. Flood damage reduction, backup water supply systems and emergency plans are measures that can contribute to increasing coping capacity. Recovery capacity can be increased by multi-source water supply, insurance, or establishing disaster funds. Adaptive capacity can be developed by starting experiments with new modes of water supply and urbanization. Including all four components of the vulnerability framework enables better understanding of water and climate related vulnerability of urban areas and enables developing more complete water management strategies to reduce vulnerability.  相似文献   

Analyses on granular mass movement mechanics and deformation with distinct element numerical modeling: implications for large-scale rock and debris avalanches     

Nick Thompson  Matthew R. Bennett  Nick Petford 《Acta Geotechnica》2009,4(4):233-247

A large-scale avalanche of Earth material is modeled here as a granular flow using a distinct element numerical model PFC ^2D. Such failures occur in a variety of geological settings and are known to occur frequently over geologic time-scales transporting significant volumes of material basinward. Despite this, they remain poorly understood. The model used here begins with a listric failure, typical of the flank collapse of a volcanic cone, and describes the movement of an assembly of several thousand particles from failure to deposition. Within the model, each particle possesses its own material properties and interacts with its immediate neighbors and/or the basal boundary during emplacement. The general mechanics of the particle assembly are observed by monitoring the stresses, displacements, and velocities of distinct sections of the avalanche body. We monitor the avalanches’ energy regime (e.g., gravitational influence, energy dissipation by friction, kinetic energy evolution, and avalanche body strain). The addition of colored markers of varying geometry to the pre-failure avalanche was also used to make qualitative observations on the internal deformation that occurs during avalanche emplacement. A general stretching and thinning of the avalanche is observed. Monitoring of vertical and horizontal variations in stress, strain, porosity, and relative particle stability indicate that the lower more proximal sections of the avalanche are subject to higher stresses. These stresses are observed to be most significant during the initial phases of failure but decline thereafter; a situation likely to be conducive to block fragmentation and in developing a basal shear layer in real-world events. The model also shows how an avalanche which is initially influenced purely by gravity (potential energy) develops into a fully flowing assemblage as downslope momentum is gained and kinetic energy increases. The horizontal transition where the failure meets the run-out surface is recognized as a key area in emplacement evolution. The model has particular relevance to volcanic flank collapses and consequently the implications of the model to these types of failure and the geological products that result are considered in detail although the model is relevant to any form of large-scale rock or debris avalanche.  相似文献   

Discussion of “Neuro-fuzzy models employing wavelet analysis for suspended sediment concentration prediction in rivers”     

Robert J. Abrahart  Nick J. Mount 《水文科学杂志》2013,58(7):1325-1329

Citation Abrahart, R.J. & Mount, N.J. (2011) Discussion of “Neuro-fuzzy models employing wavelet analysis for suspended sediment concentration prediction in rivers by S.A. Mirgagheri et al. (2010, Hydrol. Sci. J. 55(7), 1175–1189).” Hydrol. Sci. J. 56(7), 1325–1329.  相似文献   

The Seasonal Prediction of the Exceptional Yangtze River Rainfall in Summer 2020     

Chaofan LI  Riyu LU  Nick DUNSTONE  Adam A.SCAIFE  Philip E.BETT  Fei ZHENG 《大气科学进展》2021,38(12):2055-2066

During June and July of 2020, the Yangtze River basin suffered from extreme mei-yu rainfall and catastrophic flooding. This study explores the seasonal predictability and associated dynamical causes for this extreme Yangtze River rainfall event, based on forecasts from the Met Office GloSea5 operational forecast system. The forecasts successfully predicted above-average rainfall over the Yangtze River basin, which arose from the successful reproduction of the anomalous western North Pacific subtropical high (WNPSH). Our results indicate that both the Indian Ocean warm sea surface temperature (SST) and local WNP SST gradient were responsible for the westward extension of the WNPSH, and the forecasts captured these tropical signals well. We explore extratropical drivers but find a large model spread among the forecast members regarding the meridional displacements of the East Asian mid-latitude westerly jet (EAJ). The forecast members with an evident southward displacement of the EAJ favored more extreme Yangtze River rainfall. However, the forecast Yangtze River rainfall anomaly was weaker compared to that was observed and no member showed such strong rainfall. In observations, the EAJ displayed an evident acceleration in summer 2020, which could lead to a significant wind convergence in the lower troposphere around the Yangtze River basin, and favor more mei-yu rainfall. The model forecast failed to satisfactorily reproduce these processes. This difference implies that the observed enhancement of the EAJ intensity gave a large boost to the Yangtze River rainfall, hindering a better forecast of the intensity of the event and disaster mitigation.  相似文献   

Changes in daily climate extremes in China and their connection to the large scale atmospheric circulation during 1961–2003     

Qinglong You  Shichang Kang  Enric Aguilar  Nick Pepin  Wolfgang-Albert Flügel  Yuping Yan  Yanwei Xu  Yongjun Zhang  Jie Huang 《Climate Dynamics》2011,36(11-12):2399-2417

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Relationship among titanium,rare earth elements,U–Pb ages and deformation microstructures in zircon: Implications for Ti-in-zircon thermometry     

Nick E. Timms  Peter D. Kinny  Steven M. Reddy  Katy Evans  Chris Clark  Dave Healy 《Chemical Geology》2011,280(1-2):33-46

A zircon grain in an orthopyroxene–garnet–phlogopite–zircon–rutile-bearing xenolith from Udachnaya, Siberia, preserves a pattern of crystallographic misorientation and subgrain microstructure associated with crystal–plastic deformation. The zircon grain records significant variations in titanium (Ti) from 2.6 to 30 ppm that corresponds to a difference in calculated Ti-in-zircon temperatures of over several hundred degrees Celsius. The highest Ti concentration is measured at subgrain centres (30 ppm), and Ti is variably depleted at low-angle boundaries (down to 2.6 ppm). Variations in cathodoluminescence coincide with the deformation microstructure and indicate localised, differential enrichment of rare earth elements (REE) at low-angle boundaries. Variable enrichment of U and Th and systematic increase of Th/U from 1.61 to 3.52 occurs at low-angle boundaries. Individual SHRIMP-derived U–Pb ages from more deformed zones (mean age of 1799 ± 40, n = 22) are systematically younger than subgrain cores (mean age of 1851 ± 65 Ma, n = 7), and indicate that open system behaviour of Ti–Th–U occurred shortly after zircon growth, prior to the accumulation of significant radiogenic Pb. Modelling of trace-element diffusion distances for geologically reasonable thermal histories indicates that the observed variations are ~ 5 orders of magnitude greater than can be accounted for by volume diffusion. The data are best explained by enhanced diffusion of U, Th and Ti along deformation-related fast-diffusion pathways, such as dislocations and low-angle (< 5°) boundaries. These results indicate chemical exchange between zircon and the surrounding matrix and show that Ti-in-zircon thermometry and U–Pb geochronology from deformed zircon may not yield information relating to the conditions and timing of primary crystallisation.  相似文献